高等学校化学学报 ›› 1995, Vol. 16 ›› Issue (S1): 177.
YANG Chu-lo, QIN Jin-gui, LIU Dao-yu
YANG Chu-lo, QIN Jin-gui, LIU Dao-yu
摘要:
In order to study the relationship between structure and conductivity, ten new organometallic radical ionic salts. [CpFeBz]n[M(mnt)2] and [CpFeBz]n[M(dmit)2] (M=Ni, Pd, Pt, Cu, Co; Cp=Cydopentadienyl; Bz=Benzene; H2mnt=maleonitriledithiole; H2dmit=4,5-dimercapto-1, 3-dithioie-2-thione; n=1 or 2), were synthesized according to a new synthetic route. They were characterized using elemental analysis, infrared and 1H-nuclenr magnetic reso-nance spectroscopy. The crystal structure of [CpFeBz]2[Ni(mnt)2] was determined using X-ray diffraction. The electrical conductivity of siolid stale was reported. Gomplexes of [CpFeBz]n[M(mnt)2] showed a low conductivity, while complexes of [CpKeBz]n[M(dmit)2] exhibited a rather high conductivity in the range of 10-1-10-2S·cm-1.
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