高等学校化学学报 ›› 1980, Vol. 1 ›› Issue (2): 117.

• 论文 • 上一篇    下一篇

有机磷昆虫不育剂的研究--N-乙撑亚胺基,烷氧基(胺基,取代胺基)磷酰胺与硫代磷酰胺类化合物的合成

杨石先, 陈天池, 李玉桂, 高金生   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1979-12-27 出版日期:1980-12-24 发布日期:1980-12-24

RESEARCH ON ORGANOPHOSPHORUS COMPOUNDS--THE SYNTHESIS OF N-ETHYLENEIMINO,ALKYLOXY (AMINO, SUBSTITUTED AMINO) THIOPHOSPHORYLAMIDES

Yang Shixian(Yang Shih-hsien), Chen Tianchi, Li Yugui, Gao Jinsheng   

  1. Institute of Elemento-organic Chemistry, Nankai University
  • Received:1979-12-27 Online:1980-12-24 Published:1980-12-24

摘要: 含磷乙撑亚胺化合物的研究开始于本世纪中叶,1950年Bestian首先合成了一系列这类化合物。其中三乙撑亚胺基氧化膦(Tepa)及其硫代物(ThioTepa)以及甲基取代衍生物(Me-Tepa)。

Abstract: The present communication deals with the preparation of three groups of compounds which are synthesized according to the following chemical equation The ethyleneiminizing reaction proceeds under the lower temperatures.Some physical constants of these compounds were recorded.The LD50of compounds Ps5,and Ps9 were respectively reported as l,000mg/kg and 500 mg/kg.Their chemosterilant action for insects remains to be tested.

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