高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (6): 745.
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任镜清, 黎乐民, 徐光宪
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Ren Jingqing, Li Lemin, Xu Guangxian
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摘要: 根据由光谱数据求得的镧系元素静电排斥参数和价轨道电离势,用最小二乘法拟合出它们的半经验公式,可用以求得各种组态下的镧系元素原子和离子的未知VOIP值与未知Slater和Racah参数值。
Abstract: In the present investigation we have derived semiempirical expressions for electrostatic repulsion parameters and valence orbital ionization potentials of lanthanoid atoms and ions, through least square fitting of the results deduced from the most recent spectroscopic data. These expressions can be used to estimate the unknown VOIP and unknown Slater and Racah parameters of various configurations of lahthanoid atoms and ions.
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任镜清, 黎乐民, 徐光宪. 镧系元素的静电排斥参数和价轨道电离势的半经验公式. 高等学校化学学报, 1983, 4(6): 745.
Ren Jingqing, Li Lemin, Xu Guangxian. SEMI-EMPIRICAL EXPRESSIONS FOR ELECTROSTATIC REPULSION PARAMETERS AND VALENCE ORBITAL IONIZATION POTENTIALS OF LANTHANOID ATOMS AND IONS. Chem. J. Chinese Universities, 1983, 4(6): 745.
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