高等学校化学学报

高等学校化学学报 ›› 1983, Vol. 4 ›› Issue (5): 535.

• 论文 •    下一篇

硝酸铈(Ⅳ)的十八元六氮大环配合物

王耕霖, 张若桦, 姜宗慧   

  1. 南开大学化学系
  • 收稿日期:1982-03-27 出版日期:1983-10-24 发布日期:1983-10-24

CERIUM (Ⅳ) NITRATE COORDINATION COMPOUND CONTAINING A 18-MEMBERED HEXAAZA MACROCYCLIC LIGAND

Wang Genglin, Zhang Ruohua, Jiang Zonghui   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1982-03-27 Online:1983-10-24 Published:1983-10-24

PDF (PC)

被引次数

7

摘要： 2,6-二乙酰吡啶和乙二胺在Ce(Ⅳ)的“模板”作用下,缩合得到一个新的Ce(Ⅳ)的十八元六氮大环配合物Ce(NO3)4·L·3H2O,并对其光谱,电导和稳定性进行了研究。

Abstract: A novel coordination compound of hexadentate nitrogen donor macro-cycle, Ce(NO3)4L3H2O, was obtained by the condensation of 2,6-diace-tyl-pyridine with ethylenedamine using Ce(Ⅳ) as template agent. The properties of spectra, electrical conductance and stability etc. were studied.

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