高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (12): 1072.
• 研究快报 • 上一篇 下一篇
顾翼东, 刘本耀
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Gu Yidong, Liu Benyao
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摘要： 关于有机膦、胂合钨、钼聚多酸盐的制备,文献已有若干记载。这类化合物具有“柄状”的结构。所用钨、钼的反应物是Na2WO4、Na2MoO4(有时用MoO3或Na6Mo7O24),与有机膦酸或胂酸在增加或减低酸度时反应而得到这些柄状化合物。实验表明,从聚多酸盐逐步提高pH值的途径对有机胂柄状物产量有利。
Abstract: B2[(Me2As)Mo4O15H]and B4[(RP)2Mo5O21]types of compounds were first prepared by M.T.Pope in1975 and 1976[1].Thereafter,the preparation of polytungstates and polymolybdates with organo-phosphonates and-arsonates "handles" has been in rapid progress[2].The potential uses of such compounds as antiviral and biological agents have been noted.
TrendMD:
顾翼东, 刘本耀. 解聚法制备有机胂、(月弟)合钨聚多酸盐及聚合法制备相应钼聚多酸盐的研究. 高等学校化学学报, 1986, 7(12): 1072.
Gu Yidong, Liu Benyao . Degradation Method for Preparing Organo-Arsenic and-Antimony Polytungstates, and Comparative Study of Corresponding Polymolybdates. Chem. J. Chinese Universities, 1986, 7(12): 1072.
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http://www.cjcu.jlu.edu.cn/CN/Y1986/V7/I12/1072
