高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (4): 297.

• 研究论文 • 上一篇    下一篇

Co(Ⅱ)、Ni(Ⅱ)同‘四氧二氮'大环配合物的研究(Ⅲ)—Co(Ⅱ)离子同1,7,10,16-四氧杂-4,13-二氮杂环十八烷固休配合物的合成和性质

王耕霖, 闫世平, 廖代正, 尹富玲   

  1. 南开大学化学系
  • 收稿日期:1984-11-22 出版日期:1986-04-24 发布日期:1986-04-24
  • 基金资助:

    中国科学院科学基金

Studies on the Complexes of Co(Ⅱ) and Ni(Ⅱ) Ions with 'O4N2' Macrocyclic ligand(Ⅲ)—Syntheses and Properties of the Complexes of Co(Ⅱ) with 'O4N2' Macrocyclic Ligand

Wang Genglin, Yan Shiping, Liao Daicheng, Yin Fuling   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1984-11-22 Online:1986-04-24 Published:1986-04-24

摘要: 合成了四个Co(Ⅱ)离子同1,7,10,16-四氧杂-4,13-二氮杂环十八烷的固体配合物。经IR、电子光谱、电导、DTA-TG、磁性以及元素分析等推算了它们的组成,指派了谱带的归属,并从电子光谱数据用配位场方法计算了Dq值、B值和β值,计算结果与实验观察值相符。

Abstract: The complexes of CoCl2·6H2O, Co(NCS)2·2-3H2O, Co(NO3)2·6H2O Co(ClO4)·4-5H2Owith 'O4N2' macrocyclic ligand have been prepared in solid state and characterized by elemental analyses, IR. DTA-TG, electrical conductance, visible and near infrared solid reflectance spectrum as well as magnetic moments. The absorption bands of d-d electron transitions were assigned, and values of Dq and Bwere calculated.

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