高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (11): 1039.

• 研究论文 • 上一篇    

γ-Fe2O3悬浮液分散度的流变研究

马季铭, 徐勇   

  1. 北京大学化学系
  • 收稿日期:1984-07-25 出版日期:1985-11-24 发布日期:1985-11-24

Rheometric Study on the Dispersity of γ-Fe2O3 Suspensions

Ma Jiming, Xu Yong   

  1. Department of Chemistry, Peking University, Beijing
  • Received:1984-07-25 Online:1985-11-24 Published:1985-11-24

摘要: 本工作研究了y-Fe2O3在高分子溶液中的悬浮液的流变性质,根据Mooney公式,自粘度随浓度的变化得出了悬浮液的特性粘数,并据此估算了悬浮液中的絮团大小与组成,测定了不同高分子粘合剂和表面活性剂对悬浮液分散度的影响,并提出了絮团结构模型以解释实验结果。

Abstract: In present work the viscosity of suspensions of γ-Fe2O3 particles in polymer solutions have been measured as a function of concentration at shear rates Dfrom 21.2 sec-1 to 571 sec-1. The intrinsic viscosity,[η] ,derived from the concentration dependence of the viscosity by using Mooney equation, was found to decrease with increasing shear rate. The floc size, estimated from the [η] and a theoretical treatment of floc growth by vold, was consistent with the result obtained from sedimentation ratcs. The effects of various polymer adhesives and surfactants on the dispersity of suspensions were determined. It was found that, the intrinsic viscosities of γ-Fe2O3 suspensions containing different polymer adhesives showed a great divergence at low shcar rate, but reached an about the same value at infinite shear rale. The addition of surfactants decreased the [η], but increased slightly the [η] at low shear rate. Astructural model of the floc was proposed to interpret the experimental results.

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