高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (4): 343.

• 研究论文 • 上一篇    下一篇

六水合硝酸镧在乙醇中积分溶解热之测定

张正工1, 张泉珍2, 朱盛华2   

  1. 1. 西安医学院;
    2. 西北大学化学系
  • 收稿日期:1983-11-28 出版日期:1985-04-24 发布日期:1985-04-24

Measurement of Integral Heat of Solution of La(NO3)3·6H2O in Ethanol

Zhang Zhcnggong1, Zhang Quanzhcn2, Zhu Shcnghua2   

  1. 1. Xi'an Medical College, Xi'an;
    2. Northwestern University, Xi'an
  • Received:1983-11-28 Online:1985-04-24 Published:1985-04-24

摘要: 采用波波夫型外套等温量热计,已测得一级标准KCl在水中的积分溶解热为ΔH298=17532J/mol±0.1%.此结果与米献科报导的结果相一致,证明此仪器本身是可靠的.用此仪器测得La(NO3)3·6H2O在乙醇中的积分溶解热为ΔH298=9.713±0.2KJ/mol.

Abstract: The integral heat of solution of KGl (1 class, standard grade) in water was measured by using the Popoff's isothermal jacket calorimeter. The value obtained is △H = 17523J/mol ± 0.1%. This result is in agreement with that reported by P. K. Mishenko & proves that the instrument used is reliable. By using this instrument, the integral heat of solution of La(NO3)3·6H2Oin ethanol was measured to be△H= 9.713±0.2KJ/mol.

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