高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (11): 1050.

• 研究简报 • 上一篇    

高压下聚苯胺高分子导电性的研究

许大鹏1, 崔硕景1, 苏文辉1, 王佛松2, 王生龙2   

  1. 1. 吉林大学物理系;
    2. 中国科学院长舂应用化学研究所
  • 收稿日期:1986-04-28 出版日期:1987-11-24 发布日期:1987-11-24
  • 基金资助:

    国家教委博士点基金

The Investigation of Electric Conductivity for the Poly-Aniline Complexes Under High Pressure

Xu Dapeng1, Cui Shuojing1, Su Wenhui1, Wang Fusong2, Wang Shenglong2   

  1. 1. Department of Physics, Jilin University, Changchun;
    2. Changchun Institute of Applied Chemistry, Academia Sicina, Changchun
  • Received:1986-04-28 Online:1987-11-24 Published:1987-11-24

摘要: 近年来有机聚合物导体的研究,普遍得到了世界各国的重视,目前对聚苯胺等大分子聚合物的分子结构尚未完全确定,有关担负输运电荷的载流子类型及其形成的原因等电学性质的研究,对进一步了解聚合物的分子结构,导电机理及发展导电性良好的新型高分子材料的应用,都有十分重要的意义。

Abstract: The electric conductivity for the poly-aniline with large conjugated π-bonds under high pressure was studied. Results show that a minimum of electric resistance-pressure curve for the PA-H+occurs at p = 35kbar. Consequently, the PA-H+may be used as a pressure-calibration material of p= 35kbar.At various pressure conditions, the voltage-current curves are non-linear.

TrendMD: