正态分布脂肪醇壬乙氧基醚混合溶液的表面吸附与胶束形成

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (9): 835.

正态分布脂肪醇壬乙氧基醚混合溶液的表面吸附与胶束形成

夏纪鼎, 孙岩, 周合云

无锡轻工业学院化工系

收稿日期:1986-04-10 出版日期:1987-09-24 发布日期:1987-09-24

Surface Adsorption and Micelle Formation of 9-Ethoxy--Fatty Alcohols with Gaussian Distribution of Carbon Chain Length in Aqueous Solution

Xia Jiding, Sun Yan, Zhou Heyun

Department of Chemical Engineering, Wuxi Institute of Light Industry, Wuxi

Received:1986-04-10 Online:1987-09-24 Published:1987-09-24

摘要/Abstract

摘要： 正态分布的C₁₀-C₁₈脂肪醇壬乙氧基醚(AE₉)多元混合溶液的热力学参数,按正规溶液非理想混合式计算更符合实际。调节憎水基烷基链长的分布,可有效地提高组份间的协合作用。

Abstract: The effects of different carbon chain length with Gaussian distribution of 9-ethyoxy-fatty alcohol(AE₉) on the surface adsorption, micelle formation were studied. Experimental results indicate that regular solution theory with nonideal miximg rule seems to be more reasonable than ideal mixing in calculating therm-odynamic parameters of this system. The efficiency and effectiveness of surface tension reduction and synergestic effect of mixed AE₉solution can be increased by adjusting properly the carbon chain length distribution of polyoxyethylenated fatty alcohols.

TrendMD:

夏纪鼎, 孙岩, 周合云. 正态分布脂肪醇壬乙氧基醚混合溶液的表面吸附与胶束形成. 高等学校化学学报, 1987, 8(9): 835.

Xia Jiding, Sun Yan, Zhou Heyun . Surface Adsorption and Micelle Formation of 9-Ethoxy--Fatty Alcohols with Gaussian Distribution of Carbon Chain Length in Aqueous Solution. Chem. J. Chinese Universities, 1987, 8(9): 835.