高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (7): 580.

• 论文 • 上一篇    下一篇

粉状白钨酸的研究(Ⅹ)--粉状白钨酸的离子交换性能

朱思三, 杨勇, 顾翼东   

  1. 复旦大学化学系
  • 收稿日期:1986-01-31 出版日期:1987-07-24 发布日期:1987-07-24

Studies on White Powdery Tungstic Acid(Ⅹ)--Ion Exchange Properties of white Powdery Tungstic Acid

Zhu Sisan, Yang Yong, Gu Yidong(Yih-Tong Ku)   

  1. Department of Chemistry Fudan University, Shanghai
  • Received:1986-01-31 Online:1987-07-24 Published:1987-07-24

摘要: 通过粉状白钨酸和黄钨酸的离子交换性能的测定,比较了它们之间化学活性的相对大小。用动态法(交换柱法)测得了它们的离子交换容量,计算了与钨原子相联的羟基数目。并用静态法(振荡平衡法)测定了白钨酸对不同阳离子的交换情况及各种鸽酸的pH滴定曲线。

Abstract: White powdery tungstic acid, which is considerably more active than yellow tungstic acid, was prepared under low acidity fay "the reversed way of acidification" in 1981, Aseries of compounds containing tungsten has thereby been prepared from the white powdery tungstic acid by virtue of the activities caused by the OHgroups connected directly to the tungsten atoms in the white powdery tungstic acid.The ion exchange properties of white and yellow powdery tungstic acids were therefore studied and used to compare their relative activities.In the method of Dynamic State, ion exchange capacities of both the tungstic acids were determined by use of exchange column, thereby the number of OHgroups connected with tungsten atoms were estimated. In the white powdery tungstic acid, isolated after two hours, digestion, about every two tungsten atoms are connected with one OH group, while about 25 tungsten atoms are connected to one active OH group only in the yellow tungstic acid.The more the ratio of OH group connected to the tungsten atom, the higher is the ion exchange capacity, and thus the more is the chemical activity.The ion exchange capacities of white powdery tungstic acid for several cation ions have also been studied by the method of shaking equilibrium (Method of Static State). The pHtitration curves of various tungstic acids have also been examined.

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