二-对异丙基亚砜的合成及用纸色谱法研究其萃取和分离性能

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (3): 230.

二-对异丙基亚砜的合成及用纸色谱法研究其萃取和分离性能

许晓文, 李玲颖, 高冬君, 肖振平

南开大学化学系

收稿日期:1986-09-30 出版日期:1988-03-24 发布日期:1988-03-24

Synthesis of Di-p-Isopropylphenyl Sulf oxide and Study on It's Separation and Extraction Behavior by Paper Chromatography

Xu Xiaowen, Li Lingying, Gao Dongjun, Xiao Zhenpin

Department of Chemistry, Nankai University, Tianjin

Received:1986-09-30 Online:1988-03-24 Published:1988-03-24

摘要/Abstract

摘要： 用Friedel-Crafts反应合成了二-对异丙笨亚砜,确定了它的组成和结构,测试了近紫外吸收光谱、薄层色谱行为。用反相纸色谱法在HCl和HNO₃中观察了它对40余种离子的革取能力,并在纸上分离了Au-Pd、Au-Ag、Au-Pt、Au-Tl、Os-Ru、Os-Ir、Zr-Hf、Mo-W等离子对。

Abstract: In this paper di-p-isopropylphenyl sulfoxide (PlPSO) was first synthesized by Friedel-Crafts reaction.The elemental composition and the structural characteristics of this suifoxide were determined by elemental analysis, ¹H NMR, ¹³CNMR, and IR.It's UVspectrum and TLCbehavior were also investigated.It's extraction behavior to more than 40 metallic ions in both HCl and.HNO₃ systems were observed by reversed paper chromatography.It could be used as a stationary phase in the reversed paper chromatography successfully to separate some metal ion couples, such as Au-Pd, Au-Ag, Au-Pt, Au-Tl, Os-Ru, Os-Ir, Zr-Hf, Mo-W and others.

TrendMD:

许晓文, 李玲颖, 高冬君, 肖振平. 二-对异丙基亚砜的合成及用纸色谱法研究其萃取和分离性能. 高等学校化学学报, 1988, 9(3): 230.

Xu Xiaowen, Li Lingying, Gao Dongjun, Xiao Zhenpin . Synthesis of Di-p-Isopropylphenyl Sulf oxide and Study on It's Separation and Extraction Behavior by Paper Chromatography. Chem. J. Chinese Universities, 1988, 9(3): 230.