高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (3): 400.

• 论文 • 上一篇    下一篇

5-对羟基苯基-10,15,20-三对甲氧基苯基卟啉镍LB膜的研制与表征

杨孔章, 刘艳, 冯绪胜, 董玉林   

  1. 山东大学胶体与界面化学研究所, 250100
  • 收稿日期:1989-07-29 出版日期:1991-03-24 发布日期:1991-03-24
  • 通讯作者: 杨孔章
  • 基金资助:

    国家自然科学基金

Preparation and Characterization of LB Film of Ni(Ⅱ) Complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin

Yang Kong-zhang, Liu Yan, Feng Xu-sheng, Dong Yu-lin   

  1. Institute of Colloid and Interface Chemistry, Shandong University, Jinan, 250100
  • Received:1989-07-29 Online:1991-03-24 Published:1991-03-24

PDF (PC)

被引次数

25

摘要： 近年来具有特定功能的卟啉、酞青衍生物LB膜制备的成功,为其在光学、微电子学、光电化学、化学生物传感器和模拟生物过程中的广泛应用开辟了新的途径。

关键词: 5-对羟基苯基-10, 15, 20-三对甲氧基苯基卟啉, 卟啉镍合物, LB膜

Abstract: The Ni(n) complex of 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin was prepared. The composition and structure of the complex were identified by elemental analysis, UVand 1R spectrometry. The thermostability of the complex was determined with thermogravimetry. The procedure of deposition and influence of pHon the formation of the films were also studied. The uniformity of the films was varified by angle resolved XPS spectra. The difference of spectra(UV-Vis) of molecules in LBfilms and in the solution was indicated. The crosswise resistance of monolayer films was determined.

Key words: 5-(p-hydroxyphenyl)-10,15,20-tris(p-methoxyphenyl)porphyrin, Nickel Complex of porphyrin, LB films

TrendMD: