高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (3): 347.

• 论文 • 上一篇    下一篇

合成有机锗倍半硫化物的新方法

孙丽娟, 安逢龙, 白明章   

  1. 南开大学元素有机化学研究所, 300071
  • 收稿日期:1989-08-04 出版日期:1991-03-24 发布日期:1991-03-24
  • 通讯作者: 白明章

New Method for Synthesis of Organogermanium Sesquisulfides

Sun Li-juan, An Feng-long, Bai Ming-zang   

  1. Institute of Elemento-Organic Cltemistry, Ncmbai University, Tianjin, 300071
  • Received:1989-08-04 Online:1991-03-24 Published:1991-03-24

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被引次数

13

摘要： 有机锗倍半硫化物的合成是有机锗抗癌药物研究中的热点之一。在路易斯碱(如吡啶或三乙胺)存在下,经有机锗三氯化物溶液中通干燥的硫化氢气体制得有机锗倍半硫化物的方法有许多缺点,如无法计算吸收的硫化氢的量、设备复杂、操作困难并产生硫化氢臭味和毒性。

关键词: 有机锗三氟化物, 倍半硫化物, 无水硫化钠

Abstract: Anew method for synthesis of organogermanium sesquisulfides has been studied in this work. Using this method eight sesquisulfides were synthesized. Five of them are new compounds. Their compositions and structures were characterized by Elemental-Analysis, 1R and 1HNMR spec-troscopy.

Key words: Organogermanium trichloride, Sesquisulfide, Anhydrous sodium sulfide

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