N-二茂铁甲酰基-芳基羟胺及其铜(Ⅱ)螯合物的合成与表征

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (4): 478.

N-二茂铁甲酰基-芳基羟胺及其铜(Ⅱ)螯合物的合成与表征

张文, 边占喜, 李逢泽

内蒙古大学化学系, 呼和浩特, 010021

收稿日期:1990-12-28 出版日期:1992-04-24 发布日期:1992-04-24
通讯作者: 李逢泽

Synthesis and Characterization of Some N-Ferrocenoyl- arylhydroxylamines and Their Cu(Ⅱ) Chelates

ZHANG Wen, BIAN Zhan-xi, LI Feng-ze

Department of Chemistry, Inner Mongolia University, Huhehaote, 010021

Received:1990-12-28 Online:1992-04-24 Published:1992-04-24

摘要/Abstract

摘要： 二茂铁甲酰羟胺衍生物分子中含有N-羟基和α-羰基,可与过渡金属形成螯合物.我们试图将该类螯合物用作复合固体推进剂的燃速调节剂,为此,研究了该类化合物的合成方法及其性质,并使它们与铜(Ⅱ)螯合制成铜螯合物.

关键词: 二茂铁甲酰化, 芳基羟胺, 铜二茂铁甲酰基芳基羟胺螯合物

Abstract: A series of N-ferrocenoylarylhydroxylamines have been synthesized by the partial acy-lation of arylhydroxylamines with the ferrocenoyl chloride.These organometallic compounds can act as ligands for metal chelation and their Cu(Ⅱ) chelates have been isolated.The ligands and chelates have been characterized by elemental analysis, IR and ¹H NMRspectra.The chelates can act as solid propellant burning rate modifiers.

Key words: Ferrocenoylation, Arylhydroxylamine, Copper (Ⅱ) chelates of N-ferrocenoyl-arylhydroxylamine

TrendMD:

张文, 边占喜, 李逢泽. N-二茂铁甲酰基-芳基羟胺及其铜(Ⅱ)螯合物的合成与表征. 高等学校化学学报, 1992, 13(4): 478.

ZHANG Wen, BIAN Zhan-xi, LI Feng-ze . Synthesis and Characterization of Some N-Ferrocenoyl- arylhydroxylamines and Their Cu(Ⅱ) Chelates. Chem. J. Chinese Universities, 1992, 13(4): 478.