离子液体中树脂催化转化果糖为5-羟甲基糠醛

高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (3): 548.

离子液体中树脂催化转化果糖为5-羟甲基糠醛

杜芳, 漆新华, 徐英钊, 庄源益

南开大学环境科学与工程学院, 环境污染过程与基准教育部重点实验室, 天津 300071

收稿日期:2009-07-15 出版日期:2010-03-10 发布日期:2010-03-10
通讯作者: 漆新华, 男, 博士, 副教授, 主要从事生物质化学转化资源化研究. E-mail: qixinhua@nankai.edu.cn
基金资助:
国家自然科学基金(批准号: 20806041)资助.

Catalytic Conversion of Fructose to 5-Hydroxymethylfurfural by Ion-exchange Resin in Ionic Liquid

DU Fang, QI Xin-Hua*, XU Ying-Zhao, ZHUANG Yuan-Yi

Key Laboratory of Pollution Processes and Environmental Criteria, Ministry of Education, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China

Received:2009-07-15 Online:2010-03-10 Published:2010-03-10
Contact: QI Xin-Hua. E-mail: qixinhua@nankai.edu.cn
Supported by:
国家自然科学基金(批准号: 20806041)资助.

摘要/Abstract

摘要：

开发了以离子液体1-丁基-3-甲基咪唑氯盐([BMIM]Cl)为溶剂, 固体酸离子交换树脂NKC-9为催化剂转化果糖为5-羟甲基糠醛的绿色工艺. 在此催化体系中, 100 ℃下反应10 min时5-HMF的产率达到78.0%, 其反应时间远远小于已有文献报道的长达数小时的反应时间. 在此催化体系中, 果糖起始浓度的增加对5-HMF产率影响不大, 因而此工艺同样适用于处理高浓度的果糖溶液. 离子液体[BMIM]Cl和树脂组成的催化体系可以循环使用, 经过9次重复使用后仍能保持稳定的催化活性.

关键词: 果糖; 5-羟甲基糠醛; 离子液体; [BMIM]Cl; 离子交换树脂

Abstract:

An efficient process for the dehydration of fructose to 5-hydroxymethylfurfural(5-HMF) in ionic liquid 1-butyl-3-methyl-imidazolium chloride([BMIM]Cl) in the presence of ion-exchange resin was deve-loped. A 5-HMF yield of 78.0% was achieved in 10 min at 100 ℃, where the reaction time required was much lower than that reported in previous works for converting fructose to 5-HMF. No remarkably decrease in 5-HMF yield occurred for initial fructose concentrations up to 20%(mass fraction). The ionic liquid and ion-exchange resin could be recycled and exhibited constant activity for 9 successive trials.

Key words: Fructose; 5-Hydroxymethylfurfural; Ionic liquid; 1-Butyl-3-methyl-imidazolium chloride; Ion-exchange resin

TrendMD:

杜芳, 漆新华, 徐英钊, 庄源益. 离子液体中树脂催化转化果糖为5-羟甲基糠醛. 高等学校化学学报, 2010, 31(3): 548.

DU Fang, QI Xin-Hua*, XU Ying-Zhao, ZHUANG Yuan-Yi. Catalytic Conversion of Fructose to 5-Hydroxymethylfurfural by Ion-exchange Resin in Ionic Liquid. Chem. J. Chinese Universities, 2010, 31(3): 548.

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