高等学校化学学报 ›› 2010, Vol. 31 ›› Issue (1): 193.

• 研究论文 • 上一篇    下一篇

氨基修饰超高交联树脂对没食子酸的吸附性能

王津南1,2, 许丽1,2, 李爱民1,2, 周扬1,2, 许玲1,2   

  1. 1. 污染控制与资源化研究国家重点实验室, 南京大学环境学院, 南京 210093;
    2. 江苏省有机毒物污染控制与资源化工程技术研究中心, 南京 210038
  • 收稿日期:2009-03-20 出版日期:2010-01-10 发布日期:2010-01-10
  • 通讯作者: 王津南, 男, 博士, 讲师, 主要从事水污染控制研究. E-mail: wjnnju@163.com; 李爱民, 男, 教授, 博士生导师, 主要从事水污染控制和环境材料研究. E-mail: liaimin99@vip.sina.com
  • 基金资助:

    国家杰出青年基金(批准号: 50825802)和国家自然科学基金(批准号: 50778088)资助.

Adsorption Study of Gallic Acid by Hyper Cross-linked Resin Modified by Amino Function Groups

WANG Jin-Nan1,2*, XU Li1,2, LI Ai-min1,2*, ZHOU Yang1,2, XU Ling1,2   

  1. 1. State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China;
    2. Research Center of Organic Toxic Substance Control and Resource reuse of Jiangsu Province, Nanjing 210038, China
  • Received:2009-03-20 Online:2010-01-10 Published:2010-01-10
  • Contact: WANG Jin-Nan. E-mail: wjnnju@163.com; LI Ai-min. E-mail: liaimin99@vip.sina.com
  • Supported by:

    国家杰出青年基金(批准号: 50825802)和国家自然科学基金(批准号: 50778088)资助.

摘要:

以亲水性小分子有机酸没食子酸作为研究对象, 研究了氨基修饰超高交联树脂对没食子酸的吸附行为和机理. 结果表明, 氨基修饰超高交联树脂WJN-10对没食子酸有较高的吸附容量和吸附作用力; π-π共轭作用是树脂WJN-10吸附没食子酸主要作用力; WJN-10吸附没食子酸是物理吸附主导; 吸附速率主要受控于颗粒内扩散过程; WJN-10对没食子酸有较好的吸附-脱附性能.

关键词: 氨基修饰超高交联树脂; 没食子酸; 吸附性能

Abstract:

As typical natural organic acid of hydrophilicity and small molecule, gallic acid(GA) serves to study the adsorption act and mechanism on a new hyper cross-linked resin modified by amino function groups. The adsorption isotherm data indicates that WJN-10 show higher adsorption force and amounts of gallic acid than that of other adsorbents. Its absorption was characterized by physical absorption. Batch kinetic studies indicate that the adsorption of GA on WJN-10 could only be fitted by intra-particle diffusion model, and the intra-particle diffusion played a dominant role in the adsorption of GA. In particular, excellent adsorption and desorption performance of WJN-10 for gallic acid was shown in dynamic column assay.

Key words: Resin modified by amino function group; Gallic acid; Adsorption

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