高等学校化学学报

高等学校化学学报

• 研究论文 • 上一篇    下一篇

新型螺环树状化合物的合成

梁娅, 郭金晶, 魏荣宝   

  1. 天津理工大学化学化工学院, 天津 300191
  • 收稿日期:2006-11-15 修回日期:1900-01-01 出版日期:2007-09-10 发布日期:2007-09-10
  • 通讯作者: 魏荣宝

Synthesis of Novel Spiro-dendrimer

LIANG Ya, GUO Jin-Jing, WEI Rong-Bao*   

  1. School of Chmistry & Chemical Engineering, Tianjin University of Technology, Tianjin 300191, China
  • Received:2006-11-15 Revised:1900-01-01 Online:2007-09-10 Published:2007-09-10
  • Contact: WEI Rong-Bao

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被引次数

10

摘要： 利用环己二酮单腙芳构化反应, 得到9H, 9H, 11H, 11H, 12H, 12H-六氢化苯并[9,10]-(1H, 1H, 3H, 3H, 4H, 4H, 5H, 5H, 7H, 7H, 8H, 8H-十二氢)菲-2, 6, 10-三酮腙, 然后与季戊四醇反应, 得到9H, 9H, 11H, 11H, 12H, 12H-六氢化苯并[9,10]-(1H, 1H, 3H, 3H, 4H, 4H, 5H,5H, 7H, 7H, 8H, 8H-十二氢)菲-2,6,10-三酮缩三(2,2-二羟甲基-1,3-丙二醇), 再与9-[4-(2,6-二硫杂环己基)苯基]-3-[4-(二甲酯基甲基)苯基]-2,4,8,10-四氧杂螺[5.5]十一烷反应, 制成标题化合物. 中间体和标题化合物经过IR, 1H NMR, MS和元素分析表征.

关键词: 对苯二甲醛, 季戊四醇, 树状化合物, 1,4-环己二酮, 螺环化合物

Abstract: A novel dendrimer-9H, 9H, 11H, 11H, 12H, 12H-hexahydrobenzo[9,10]-1H, 1H, 3H, 3H, 4H, 4H, 5H, 5H, 7H, 7H, 8H, 8H-dodecahydrophenanthrene-2,6,10-trione ketal-tri-(4-(4-(3-(9-(4-(2,6-disulfo-cyclohexyl)phenyl))-2,4,8,10-tetra-oxa-spiro[5.5]undecyl))phenyl-1,1-(2,6-dioxa)cyclohexanedimethanol was conveniently synthesized by the reaction of hexahydrobenzo[9,10] dodecahydrophenanthrene-2,6,10-trione ketal-tri-2,2-dihydromethyl-1,3-propanediol with 4-(4-(3-(9-(4-(2,6-disulfo-cyclohexyl)phenyl))-2,4,8,10-tetra-oxa-spiro[5.5]undecyl))phenyl-1,1-(2,6-dioxa)cyclohexanedimethanol. Some reaction intermediates were prepared with common chemical reagent . Novel dendrimer and intermediates were identified via IR, 1H NMR and MS spectra and elemental analysis.

Key words: 1,4-Benzenedicarboxaldehyde, Pentaerythritol, Dendrimer, 1,4-Cyclohexanedione, Spiro-compound

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