高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 507.

• Synthetic Sciences • 上一篇    下一篇

Oxidation of N,N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the Corresponding Aldehyde Catalyzed by Copper(Ⅱ) Ion

REN Yan-Ping, LONG La-Sheng   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • 出版日期:2000-12-31 发布日期:2000-12-31

Oxidation of N,N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the Corresponding Aldehyde Catalyzed by Copper(Ⅱ) Ion

REN Yan-Ping, LONG La-Sheng   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Online:2000-12-31 Published:2000-12-31

PDF (PC)

摘要：

On the effort to mimick the function of galactose oxidase (GO), only three copper(Ⅰ) complexes reported can catalyze efficiently the aerobic oxidation of primary and second alcohols to the corresponding aldehydes and ketons or 1,2-glycols by oxidative C-C coupling with concomitant formation of H2O2[1-3]. However, those complexes were catalytically inactive, when using copper(Ⅱ) instead of copper(Ⅰ). We report here an example of oxidation of N, N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the corresponding aldehyde (L1O) catalytzed by copper(Ⅱ) ion.

Abstract:

On the effort to mimick the function of galactose oxidase (GO), only three copper(Ⅰ) complexes reported can catalyze efficiently the aerobic oxidation of primary and second alcohols to the corresponding aldehydes and ketons or 1,2-glycols by oxidative C-C coupling with concomitant formation of H2O2[1-3]. However, those complexes were catalytically inactive, when using copper(Ⅱ) instead of copper(Ⅰ). We report here an example of oxidation of N, N-bis(Pyridymethyl)-2-aminoethanol (LOH) to the corresponding aldehyde (L1O) catalytzed by copper(Ⅱ) ion.

TrendMD: