高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 506.
• Synthetic Sciences • 上一篇 下一篇
CHEN An-Qi, YE Jian-Jun, RUAN Yuan-Ping, ZHOU Cao-Hui
CHEN An-Qi, YE Jian-Jun, RUAN Yuan-Ping, ZHOU Cao-Hui
摘要:
Both enantiomers of 1, 1'-Bi-2-naphthol (BINOL) 1 are important chiral ligands and auxiliaries for a number of asymmetric transformations such as aldol condensations, alkylations, Diels-Alder reactions, Michael additions, epoxidations, etc. Optically pure 1 and their derivatives have also been used extensively in chiral recognition, chiral separation and construction of functionalised materials[1]. As a result the development of efficient and economic methods for the preparation of optically pure 1 has attracted much attention in recent years[2] and novel methods for the resolution of racemic 1 (Rac-1) continue to be developed.
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