高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 499.
• Synthetic Sciences • 上一篇 下一篇
PENG Yin, XIE Su-Yuan, HUANG Rong-Bin, ZHENG Lan-Sun
PENG Yin, XIE Su-Yuan, HUANG Rong-Bin, ZHENG Lan-Sun
摘要:
A new perchlorinated fused compound, 6-(p-tolyl)-6H-decachloro-benzo[cd]-pyrene 1, was synthesized with solvothermal reaction,a novel approach developed in our group. 1 is an interesting molecule for it is similar in structure to chlorinated fragment molecules of fullerenes[1]. Besides, its homologues such as 6-methyl-6H-benzo[cd]pyrenes, 6-methoxycarbonyl-6H-benzo[cd]pyrene and 6-mesyloxyl-6H-benzo[cd]pyrene[2] have been synthesized as parent hydrocarbons of benzo[cd]pyrenyl system, which were investigated for its NBMO properties[3].
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