高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 493.
• Synthetic Sciences • 上一篇 下一篇
QIN Ye-Yan, WU Ling, TANG Yan-Hong, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen
QIN Ye-Yan, WU Ling, TANG Yan-Hong, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen
摘要:
Cuboidal Molybdenum have been paid much attention due to their structural resemble with those metallic centers in some biological systems[1]. To explore the chemistry of trinuclear Mo-S cluster complexes[2], we rationally synthesized two compounds:Mo3S4(DTP)3(nicotinate)(Py)·EtOH (Ⅰ) (DTP=diethyl dithiophosphate) and Mo3S4(DTP)3(isonicotinate)(Py)·EtOH (Ⅱ) by the substitution reaction of Mo3S4(DTP)3(L)(Py) (L=ClCH2COO-, CH3COO-) with nicotinic acid and isonicotinic acid, respectively.
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