高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 492.
• Synthetic Sciences • 上一篇 下一篇
TANG Yan-Hong, WU Ling, QIN Ye-Yan, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen
TANG Yan-Hong, WU Ling, QIN Ye-Yan, KANG Yao, LI Zhao-Ji, YAO Yuan-Gen
摘要:
Since the trinuclear molybdenum cluster compound Mo3S4(DTP)3(μ-DTP)(L) (DTP=diethyldithiophosphate, L=loosely-coordinated ligand) was reported[1],a large number of monomeric trinuclear molybdenum derivatives have been synthesized from it by its diverse substitution reactions[2]. This reaction provides a useful route to design cluster complexes with specific functions. By the reaction with α, ω-dicarboxylates, we successfully synthesized the first oligomer containing two incomplete cubane-type[Mo3S4] cores formulated as[Mo3S4(DTP)3(DMF)]2[η2-μ-OOC(CH2)3COO-μ-η2]) whose molecule structure is as follows:
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