高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 488.
• Synthetic Sciences • 上一篇 下一篇
LUO Sheng-Jun, LIANG Yong-Min, MA Yong-Xiang
LUO Sheng-Jun, LIANG Yong-Min, MA Yong-Xiang
摘要:
In the past few decades, much attention has been focused on palladium-catalyzed carbonylative reactions[1,2], which is a simple method to synthesize some complicated compounds[3,4]. This kind of reactions, however, can be carried out only when the substrates are arylhalide, heteroaryl halide, alkene halide,aryltrifluoromethyl-sulfonate and hypervalent iodonium salt[5] etc. Herein, we report a palladium-catalyzed carbonylative reaction between 3,7-bis(N,N-dimethylamino)-10H-dibenz[b,e] iodinium iodide(1)[6] with alcohols (2) at ambient temperature as shown in scheme.
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