高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 475.

• Synthetic Sciences • 上一篇    下一篇

Photochemical Synthesis of Cyclopentadienyl-hexamethylbenzene-iron Tetrafluoborate

CHEN Xu-Dong   

  1. Institute of Polymer Science, Zhongshan University, Guangzhou 510275
  • 出版日期:2000-12-31 发布日期:2000-12-31

Photochemical Synthesis of Cyclopentadienyl-hexamethylbenzene-iron Tetrafluoborate

CHEN Xu-Dong   

  1. Institute of Polymer Science, Zhongshan University, Guangzhou 510275
  • Online:2000-12-31 Published:2000-12-31

PDF (PC)

摘要：

As a new type of photoinitiator, cyclopentadienyl-aryl-iron tetrafluoroborate has received much attention[1]. We[2] have improved the synthesis method of cyclopen-tadienyl-benzene-iron tetrafluoroborate reported by the literature[3,4]. This synthetic method is to reflex the mixture of ferrocene and fluid aromatic compound; the cyclopentadiene of ferrocene was replaced by the incoming aromatic compound. However, this method is rather limited if the ligands are solid aromatic compounds.

Abstract:

As a new type of photoinitiator, cyclopentadienyl-aryl-iron tetrafluoroborate has received much attention[1]. We[2] have improved the synthesis method of cyclopen-tadienyl-benzene-iron tetrafluoroborate reported by the literature[3,4]. This synthetic method is to reflex the mixture of ferrocene and fluid aromatic compound; the cyclopentadiene of ferrocene was replaced by the incoming aromatic compound. However, this method is rather limited if the ligands are solid aromatic compounds.

TrendMD: