高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 471.

• Synthetic Sciences • 上一篇    下一篇

Biomimetic Oxidation of 1-1'-Bi-2-naphthol with Copper(Ⅰ) and Copper(Ⅱ)-amine Complexes

TAN Duan-Ming, LI Hui-Hua, XU Zun-Le   

  1. Applied Chemistry Department, School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, Guangdong 510275
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 基金资助:

    Project (No. 29772057) supported by the National Natural Science Foundation of China.

Biomimetic Oxidation of 1-1'-Bi-2-naphthol with Copper(Ⅰ) and Copper(Ⅱ)-amine Complexes

TAN Duan-Ming, LI Hui-Hua, XU Zun-Le   

  1. Applied Chemistry Department, School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, Guangdong 510275
  • Online:2000-12-31 Published:2000-12-31
  • Supported by:

    Project (No. 29772057) supported by the National Natural Science Foundation of China.

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摘要：

Copper amine complexes were used to mimic oxidases in the biomimetic oxidation of organic compounds[1]. Masahiro Noji and coworkers[2] reported the oxidative coupling of 2-naphthol into high yield of 1,1'-bi-2-naphthol (1) by using catalytical amount of CuCl-tetramethylethylenediamine complex at the presence of O2. Here we report the catalytic oxidation of 1 with copper amine complexes.

Abstract:

Copper amine complexes were used to mimic oxidases in the biomimetic oxidation of organic compounds[1]. Masahiro Noji and coworkers[2] reported the oxidative coupling of 2-naphthol into high yield of 1,1'-bi-2-naphthol (1) by using catalytical amount of CuCl-tetramethylethylenediamine complex at the presence of O2. Here we report the catalytic oxidation of 1 with copper amine complexes.

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