高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 445.
• Synthetic Sciences • 上一篇 下一篇
DOU Jian-Min, LI Da-Cheng, LIU Ying, XU Li-Qiang, BI Wen-Hua
DOU Jian-Min, LI Da-Cheng, LIU Ying, XU Li-Qiang, BI Wen-Hua
摘要:
One-dimensional coordination polymers have attracted considerable interest in recent years because of the prospect of electrical, optical and magnetic properties. Crown ether can form one-dimensional infinite chain structure with transition metal complex. We synthesized the complexes of 18-crown-6 with Na2[m{S2C2(CN)2}2](m=Cu, Ni, Pd, Pt; S2C2(CN)22- mnt) and now report the structure of complex[Na(18C6)]2[Cu(mnt)2]·H2O.
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