高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 427.

• Synthetic Sciences • 上一篇    下一篇

Versatile Carborane Cages:A New Class of Metallacarboranes Incorporating the η7-Carboranyl Ligand

XIE Zuo-Wei   

  1. Departments of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
  • 出版日期:2000-12-31 发布日期:2000-12-31

Versatile Carborane Cages:A New Class of Metallacarboranes Incorporating the η7-Carboranyl Ligand

XIE Zuo-Wei   

  1. Departments of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong
  • Online:2000-12-31 Published:2000-12-31

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摘要：

The chemistry of metallacarboranes has witnessed an explosive growth since the first metallacarborane was reported in 1965. A large number of metallacarboranes of s-,p-, d-,and f-block elements are known; however, the highest hapticity of carboranyl ligands in these compounds has been six. We have recently discovered a brand new bonding mode for carborane molecules, and some recent findings in our laboratory will be presented in this paper.

Abstract:

The chemistry of metallacarboranes has witnessed an explosive growth since the first metallacarborane was reported in 1965. A large number of metallacarboranes of s-,p-, d-,and f-block elements are known; however, the highest hapticity of carboranyl ligands in these compounds has been six. We have recently discovered a brand new bonding mode for carborane molecules, and some recent findings in our laboratory will be presented in this paper.

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