高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 336.

• Chemistry in Materials Sciences • 上一篇    下一篇

Unusual Stepwise Assembly of a New Polymolybdate with Novel Building Blocks:Li12[H16Mo36O108]·48H2O

WU Chuan-De, LIN Xiang, YANG Wen-Bin, LU Can-Zhong, ZHUANG Hong-Hui   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou 350002
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 通讯作者: LU Can-Zhong E-mail:czlu@ms.fjirsm.ac.cn
  • 基金资助:

    Supported by the Chinese Academy of Sciences and the State Personnel Ministry.

Unusual Stepwise Assembly of a New Polymolybdate with Novel Building Blocks:Li12[H16Mo36O108]·48H2O

WU Chuan-De, LIN Xiang, YANG Wen-Bin, LU Can-Zhong, ZHUANG Hong-Hui   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou 350002
  • Online:2000-12-31 Published:2000-12-31
  • Contact: LU Can-Zhong E-mail:czlu@ms.fjirsm.ac.cn
  • Supported by:

    Supported by the Chinese Academy of Sciences and the State Personnel Ministry.

PDF (PC)

摘要：

Molybdenum in its higher oxidation states is easy to form poly-nuclear anionic metal-oxygen clusters, many giant polymolybdates with extraordinary variety of the relevant topology and electronic structures were reported [1].As the mechanism of the formation of complex molecular systems from simple building blocks by conservative self-assembly process is currently the subject of intense research but not yet fully understood, the synthesis of goal compound is still elusive.

Abstract:

Molybdenum in its higher oxidation states is easy to form poly-nuclear anionic metal-oxygen clusters, many giant polymolybdates with extraordinary variety of the relevant topology and electronic structures were reported [1].As the mechanism of the formation of complex molecular systems from simple building blocks by conservative self-assembly process is currently the subject of intense research but not yet fully understood, the synthesis of goal compound is still elusive.

TrendMD: