高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 334.

• Chemistry in Materials Sciences • 上一篇    下一篇

Synthesis and Structure of Hetropolyoxometal-supported Transition Metal Complexes

YU Rong-Min, CHEN Jin, LU Shao-Fang, LU Can-Zhong   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
  • 出版日期:2000-12-31 发布日期:2000-12-31

Synthesis and Structure of Hetropolyoxometal-supported Transition Metal Complexes

YU Rong-Min, CHEN Jin, LU Shao-Fang, LU Can-Zhong   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
  • Online:2000-12-31 Published:2000-12-31

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摘要：

The chemistry of metal-oxo compounds has been extensively and intensively studied for over a hundred years because of their theoritical importance and practical application[1]. Recent advance has afforded a study of inorganic or organometallic complexes containing metal-oxo anions[2]. Herein, the synthesis and structural characterization of two heteropolyoxomolybdnum-supported transition metal complexes (H2bpy)0.5Ni(H2O)5[Mo5P2O23]Ni(Hbpy)(H2O)4 (1) and (H2bpy)0.5Co(H2O)5[Mo5P2O23]Co(Hbpy) (H2O)4(2) are reported.

Abstract:

The chemistry of metal-oxo compounds has been extensively and intensively studied for over a hundred years because of their theoritical importance and practical application[1]. Recent advance has afforded a study of inorganic or organometallic complexes containing metal-oxo anions[2]. Herein, the synthesis and structural characterization of two heteropolyoxomolybdnum-supported transition metal complexes (H2bpy)0.5Ni(H2O)5[Mo5P2O23]Ni(Hbpy)(H2O)4 (1) and (H2bpy)0.5Co(H2O)5[Mo5P2O23]Co(Hbpy) (H2O)4(2) are reported.

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