高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 314.

• Chemistry in Materials Sciences • 上一篇    下一篇

Polymerization of Styrene by Thermal Scission of C-C Bond

JIN Jing1, WANG Hai-Sheng1, WU Long-Min1, ZHANG Zi-Yi1, HUANG Hong-Jun2   

  1. 1. National Laboratory of Applied Organic chemistry, Lanzhou University, Lanzhou 730000;
    2. PLA Ordnance Engineering Institute, Shijiazhuang 050003
  • 出版日期:2000-12-31 发布日期:2000-12-31

Polymerization of Styrene by Thermal Scission of C-C Bond

JIN Jing1, WANG Hai-Sheng1, WU Long-Min1, ZHANG Zi-Yi1, HUANG Hong-Jun2   

  1. 1. National Laboratory of Applied Organic chemistry, Lanzhou University, Lanzhou 730000;
    2. PLA Ordnance Engineering Institute, Shijiazhuang 050003
  • Online:2000-12-31 Published:2000-12-31

摘要:

A radical induced polymerization of syrene (St) with diethyl-2, 3-dicyano-2,3-diphenylsuccinate (1), producing ultra high molecular polystyrene wasreported herein. The polymerizations of syrene with dl-1 at 70-90℃ are shown in Figure 1. In this case, M of polymers was observer to in crease with reaction time.

Abstract:

A radical induced polymerization of syrene (St) with diethyl-2, 3-dicyano-2,3-diphenylsuccinate (1), producing ultra high molecular polystyrene wasreported herein. The polymerizations of syrene with dl-1 at 70-90℃ are shown in Figure 1. In this case, M of polymers was observer to in crease with reaction time.

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