高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 230.

• Chemistry in Materials Sciences • 上一篇    下一篇

Studies on New Hydrophobically Modified Water-soluble Cellulosic Graft Terpolymers

ZHANG Li-Ming, ZHANG Jian, LI Zhuo-Mei   

  1. Institute of Polymer Science, Zhongshan University, Guangzhou 510275
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 基金资助:

    This work was supported by the Natural Science Foundation of Guangdong Province, China (Grant Number:970171) and by the Laboratory of Cellulose & Lignocellulosic Chemistry, Academia Sinica.

Studies on New Hydrophobically Modified Water-soluble Cellulosic Graft Terpolymers

ZHANG Li-Ming, ZHANG Jian, LI Zhuo-Mei   

  1. Institute of Polymer Science, Zhongshan University, Guangzhou 510275
  • Online:2000-12-31 Published:2000-12-31
  • Supported by:

    This work was supported by the Natural Science Foundation of Guangdong Province, China (Grant Number:970171) and by the Laboratory of Cellulose & Lignocellulosic Chemistry, Academia Sinica.

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被引次数

1

摘要：

Hydrophobically modified water-soluble ion-containing cellulosic polymer possessing intra-or intermolecular modes of hydrophobic associations has been recently the object of our research[1-4]. Based on the preparation of the surface-active monomer, dimethyloctyl (2-methacryloxyethyl)ammonium bromide (DMOA), new cellulosic graft terpolymers (NCGT) have been synthesized by grafting acrylamide (AM) and DMOA onto carboxymethyl cellulose (CMC) using potassium persulfate and dimethylaminoethyl methacrylate as the initiating system, and characterized by FTIR, elementary analysis, titration and GPC. To obtain the optimum reaction conditions, the influence of the feed ratio and addition order of raw materials, the concentration of initiators, temperature and pH on the grafting have been investigated.

Abstract:

Hydrophobically modified water-soluble ion-containing cellulosic polymer possessing intra-or intermolecular modes of hydrophobic associations has been recently the object of our research[1-4]. Based on the preparation of the surface-active monomer, dimethyloctyl (2-methacryloxyethyl)ammonium bromide (DMOA), new cellulosic graft terpolymers (NCGT) have been synthesized by grafting acrylamide (AM) and DMOA onto carboxymethyl cellulose (CMC) using potassium persulfate and dimethylaminoethyl methacrylate as the initiating system, and characterized by FTIR, elementary analysis, titration and GPC. To obtain the optimum reaction conditions, the influence of the feed ratio and addition order of raw materials, the concentration of initiators, temperature and pH on the grafting have been investigated.

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