高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 213.

• Chemistry in Materials Sciences • 上一篇    下一篇

Novel One-dimensional Cyano-bridged Chain Molecular-based Magnet[Ln(DMF)4(H2O)2Mn(CN)6·H2O]n:Crystal Structure, Long-range Magnetic Ordering, High Tc and Strong Coercive Behavior

YAN Bing, CHEN Zhi-Da, WANG Shi-Xi   

  1. State Key Laboratory of Rare Earth Material Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 基金资助:

    This work was supported by the National Natural Science Foundation of China (29831010,20023005), the State Key Project of Fundamental Research of China (G1998061306) and the China Postdoctoral Science Foundation (25).

Novel One-dimensional Cyano-bridged Chain Molecular-based Magnet[Ln(DMF)4(H2O)2Mn(CN)6·H2O]n:Crystal Structure, Long-range Magnetic Ordering, High Tc and Strong Coercive Behavior

YAN Bing, CHEN Zhi-Da, WANG Shi-Xi   

  1. State Key Laboratory of Rare Earth Material Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • Online:2000-12-31 Published:2000-12-31
  • Supported by:

    This work was supported by the National Natural Science Foundation of China (29831010,20023005), the State Key Project of Fundamental Research of China (G1998061306) and the China Postdoctoral Science Foundation (25).

PDF (PC)

摘要：

There has been great interest in the study of the magnetic properties of molecular-based compounds[1,2]. In the present work, we employed N,N-dimethylformide (DMF) as a hybrid ligand to synthesize a new family of cyano-bridged complexes contain rare earth and Manganese:[Ln(DMF)4(H2O)2Mn(CN)6·H2O]n (abbreviated as LnMn, Ln=Sm, Eu, Gd, Tb, Dy, Er) and the crystal data of former three complexes has been obtained, which display a remarkable variety of magnetochemical behavior and a rich structural chemistry.

Abstract:

There has been great interest in the study of the magnetic properties of molecular-based compounds[1,2]. In the present work, we employed N,N-dimethylformide (DMF) as a hybrid ligand to synthesize a new family of cyano-bridged complexes contain rare earth and Manganese:[Ln(DMF)4(H2O)2Mn(CN)6·H2O]n (abbreviated as LnMn, Ln=Sm, Eu, Gd, Tb, Dy, Er) and the crystal data of former three complexes has been obtained, which display a remarkable variety of magnetochemical behavior and a rich structural chemistry.

TrendMD: