高等学校化学学报

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 193.

• Chemistry in Materials Sciences • 上一篇    下一篇

Oligomerization of Molybdenum Clusters via Multi-Functional Ligands

YAO Yuan-Gen   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002
  • 出版日期:2000-12-31 发布日期:2000-12-31

Oligomerization of Molybdenum Clusters via Multi-Functional Ligands

YAO Yuan-Gen   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002
  • Online:2000-12-31 Published:2000-12-31

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摘要：

Trinuclear molybdenum clusters show diversity of reactivity towards transition metals and organic ligands. For example, different ligand-substitution and additive reactions can take place at the five coordination sites of Mo3S4(DTP)3(μ-L)(L')(Ⅰ). The bridging ligand μ-L, the terminal DTP'S and the loosely-coordinated ligand L'can be replaced by many carboxylic acids and polar solvents, respectively. By this way, many hetero-metallic cluster derivatives can be synthesized.

Abstract:

Trinuclear molybdenum clusters show diversity of reactivity towards transition metals and organic ligands. For example, different ligand-substitution and additive reactions can take place at the five coordination sites of Mo3S4(DTP)3(μ-L)(L')(Ⅰ). The bridging ligand μ-L, the terminal DTP'S and the loosely-coordinated ligand L'can be replaced by many carboxylic acids and polar solvents, respectively. By this way, many hetero-metallic cluster derivatives can be synthesized.

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