高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 179.

• Chemistry in Life Sciences • 上一篇    下一篇

Transfer Gibbs Energies of[Cr(Salen)(H2O)2]BPh4 From Water to Straight-chain Alkanol

CAO Li-Xin, ZHOU Ban-Xne   

  1. Department of Science, Weihai campus, Harbin Institute of Technology, Weihai 264209
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 基金资助:

    This work was supported by a science grant from Shandong province (Grant No. Y98B02021).

Transfer Gibbs Energies of[Cr(Salen)(H2O)2]BPh4 From Water to Straight-chain Alkanol

CAO Li-Xin, ZHOU Ban-Xne   

  1. Department of Science, Weihai campus, Harbin Institute of Technology, Weihai 264209
  • Online:2000-12-31 Published:2000-12-31
  • Supported by:

    This work was supported by a science grant from Shandong province (Grant No. Y98B02021).

摘要:

Chromium(Ⅲ) is one essential nutrient that has been implicated as glucose tolerant factor(GTF) in the maintenance of normal carbohydrate and lipid metabolism. Schiff base complexes of chromium (Ⅲ) such as N,N' -ethylenebis (Salicylideneiminato) diaquochromium (Ⅲ) chloride[Cr(Salen)(H2O)2]Cl as a new kind of GTP model was shown to reduce the symptoms of diabetes significantly, hyperglycemia and cholesterol in diabetic rates[l]. After studied the decomposition and characterization of[Cr(Salen)(H2O)2]Cl[2], a new confound of[Cr(Salen)(H2O)2]BPh4 is prepared and its transfer Gibbs energies(Δtr Go) from water to strait-chain Alkanols is studied in order to understand the thermodynamic properties of[Cr(Salen)(H2O)2]+ in different solvents.

Abstract:

Chromium(Ⅲ) is one essential nutrient that has been implicated as glucose tolerant factor(GTF) in the maintenance of normal carbohydrate and lipid metabolism. Schiff base complexes of chromium (Ⅲ) such as N,N' -ethylenebis (Salicylideneiminato) diaquochromium (Ⅲ) chloride[Cr(Salen)(H2O)2]Cl as a new kind of GTP model was shown to reduce the symptoms of diabetes significantly, hyperglycemia and cholesterol in diabetic rates[l]. After studied the decomposition and characterization of[Cr(Salen)(H2O)2]Cl[2], a new confound of[Cr(Salen)(H2O)2]BPh4 is prepared and its transfer Gibbs energies(Δtr Go) from water to strait-chain Alkanols is studied in order to understand the thermodynamic properties of[Cr(Salen)(H2O)2]+ in different solvents.

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