高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 157.

• Chemistry in Life Sciences • 上一篇    下一篇

A Novel Iron(Ⅲ)-nickel(Ⅱ) Heterodinuclear Complex as Structural Core Models for Dimetalloenzymes

YIN Li-Hua, CHENG Peng, YAN Shi-Ping   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • 出版日期:2000-12-31 发布日期:2000-12-31

A Novel Iron(Ⅲ)-nickel(Ⅱ) Heterodinuclear Complex as Structural Core Models for Dimetalloenzymes

YIN Li-Hua, CHENG Peng, YAN Shi-Ping   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • Online:2000-12-31 Published:2000-12-31

摘要:

The study of heterodimetallic complexes is interesting in regard to their potential in modeling the structures and reactivities of metalloenzymes containing two distinct metal ions (such as[NiFe] hydrogenase and purple acid phosphatase) in their active sites. However, the preparation of mixed-metal complexes is often a considerable challenge.

Abstract:

The study of heterodimetallic complexes is interesting in regard to their potential in modeling the structures and reactivities of metalloenzymes containing two distinct metal ions (such as[NiFe] hydrogenase and purple acid phosphatase) in their active sites. However, the preparation of mixed-metal complexes is often a considerable challenge.

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