高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 133.
• Chemistry in Energy Sciences • 上一篇 下一篇
WU Ting-Hua1, YAN Qian-Gu2, CHAO Zi-Sheng2, LUO Chun-Rong2, YE Jian-Liang2, WAN Hui-Lin2
WU Ting-Hua1, YAN Qian-Gu2, CHAO Zi-Sheng2, LUO Chun-Rong2, YE Jian-Liang2, WAN Hui-Lin2
摘要:
In our previous work, POM has been investigated by the pulse reaction with CH4 and CH4/O2 respectively, on Rh/SiO2 catalyst. Kinetic isotopic effect was also studied by using CD4 and CD4/O2. The results suggest that POM may proceed most possibly via a mechanism of surface carbon species reacting with surface oxygen. In the present work, 1H MAS NMR was utilized to investigate the POM mechanism in aiming of presenting additional evidence.
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