高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (S1): 115.

• Chemistry in Energy Sciences • 上一篇    下一篇

Pre-reduced Activated Carbon-Supported Molybdenum-Based Catalysts for the Production of Mixed Alcohols from Synthesis Gas

LI Xian-Guo, FENG Li-Juan   

  1. Department of Applied Chemistry, Ocean University of Qingdao, Qingdao 266003
  • 出版日期:2000-12-31 发布日期:2000-12-31
  • 基金资助:

    This work was partly supported by SRF for ROCS, State Education Ministry of China.

Pre-reduced Activated Carbon-Supported Molybdenum-Based Catalysts for the Production of Mixed Alcohols from Synthesis Gas

LI Xian-Guo, FENG Li-Juan   

  1. Department of Applied Chemistry, Ocean University of Qingdao, Qingdao 266003
  • Online:2000-12-31 Published:2000-12-31
  • Supported by:

    This work was partly supported by SRF for ROCS, State Education Ministry of China.

摘要:

Unsupported or supported Mo-based catalysts have been widely employed in petroleum industry, for hydrotreating[1],and for the production of hydrocarbons[2] and alcohols[3] by hydrogenation of CO (or CO2). Oxides, such as alumina, silica, silica-alumina, are commonly used as the supports for these purposes. Carbon-supported materials have been claimed to have potential advantages over oxide-supported ones, such as lower tendency of carbon deposition[4], less dehydration and thus less secondary reactions. Here we present results on mixed alcohol synthesis over H2-prereduced C-supported Mo-based catalysts.

Abstract:

Unsupported or supported Mo-based catalysts have been widely employed in petroleum industry, for hydrotreating[1],and for the production of hydrocarbons[2] and alcohols[3] by hydrogenation of CO (or CO2). Oxides, such as alumina, silica, silica-alumina, are commonly used as the supports for these purposes. Carbon-supported materials have been claimed to have potential advantages over oxide-supported ones, such as lower tendency of carbon deposition[4], less dehydration and thus less secondary reactions. Here we present results on mixed alcohol synthesis over H2-prereduced C-supported Mo-based catalysts.

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