功能性多吡啶配体的合成

高等学校化学学报 ›› 2000, Vol. 21 ›› Issue (3): 395.

功能性多吡啶配体的合成

敬炳文, 吴韬, 张曼华, 沈涛

中国科学院感光化学研究所, 北京 100101

收稿日期:1999-05-05 出版日期:2000-03-24 发布日期:2000-03-24
通讯作者: 张曼华(1939年出生),女,研究员,博士生导师,从事有机光化学研究.
基金资助:
国家自然科学基金(批准号:59783007)

Synthesis of the Polypyridine Ligands with Functional Groups

JING Bing-Wen, WU Tao, ZHANG Man-Hua, SHEN Tao

Institute of Photographic Chemistry, the Chinese Academy of Sciences, Beijing 100101, China

Received:1999-05-05 Online:2000-03-24 Published:2000-03-24

摘要/Abstract

摘要： 经过多步反应,合成了10个新的多吡啶配体,其中,有带强吸附性的基团(磷酸基、羧基),有对pH敏感及具有平面大共轭体系的联多吡啶配体及其中间体,用光谱鉴定了它们的结构.

关键词: 功能性配体, 多吡啶配体, Pd(0)催化, 配体合成

Abstract: Several new polypyridine ligands containing functional groups such as PO₃H₂, COOH, pHsensitive groups are synthesized and characterized with the purpose of developing new functional polypyridine complexes.

Key words: Functional group, Polypridine ligand, Pd(0) catalysis, Synthesis of ligand

中图分类号:

O621

TrendMD:

敬炳文, 吴韬, 张曼华, 沈涛. 功能性多吡啶配体的合成. 高等学校化学学报, 2000, 21(3): 395.

JING Bing-Wen, WU Tao, ZHANG Man-Hua, SHEN Tao . Synthesis of the Polypyridine Ligands with Functional Groups. Chem. J. Chinese Universities, 2000, 21(3): 395.