高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 95.
• Organic Synthesis Chemistry • 上一篇 下一篇
Tong-Shuang Li1,2, Li-Jun Li1,2
Tong-Shuang Li1,2, Li-Jun Li1,2
摘要: Under catalysis of montmorillonites, arenes could be cholesterylated by cholesterol (1) via a Friedel-Crafts alkylation.1 When phenols were employed as substrates for that reaction, aryl cholesteryl ethers were obtained instead of aryl cholestenes.2 However, β-naphthol (2a) and α-naphthol (2b) gave obviously different products. We report here the identification of these unexpected products from the reaction of 2 with 1 catalysed by montmorillonite K 10.
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