高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 66.

• Organic Synthesis Chemistry • 上一篇    下一篇

Cycloaddition of Bun3P·CS2 with Azo Compounds

Xiaodong Chen1, Yuxiu Liu2, Ruzhen Cao2, Lunzu Liu2   

  1. 1. Dandong Normal Teacher's College, Liaoning, Dandong 118003;
    2. Institute of Elemento-Organic Chemistry, Nankai University(Tianjin 300071)National Key Laboratory of Elemento-Organic Chemistry
  • 出版日期:1998-12-31 发布日期:1998-12-31

Cycloaddition of Bun3P·CS2 with Azo Compounds

Xiaodong Chen1, Yuxiu Liu2, Ruzhen Cao2, Lunzu Liu2   

  1. 1. Dandong Normal Teacher's College, Liaoning, Dandong 118003;
    2. Institute of Elemento-Organic Chemistry, Nankai University(Tianjin 300071)National Key Laboratory of Elemento-Organic Chemistry
  • Online:1998-12-31 Published:1998-12-31

摘要: Cycloadditions of Bun3P·CS2 Ⅰ with electron-deficient alkynes have been studied, but reactions with double bonds have only been confined to maleic anhydride, N-phenylmaleimide[1] and norbomene analogs[2]. In this paper we describe the first examples of cycloadditions of Ⅰ to heteroatom double bonds.

Abstract: Cycloadditions of Bun3P·CS2 Ⅰ with electron-deficient alkynes have been studied, but reactions with double bonds have only been confined to maleic anhydride, N-phenylmaleimide[1] and norbomene analogs[2]. In this paper we describe the first examples of cycloadditions of Ⅰ to heteroatom double bonds.

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