高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 480.

• Physical Organic Chemistry • 上一篇    下一篇

Photosensitization of Two-dimensional Conjugated Polymers of Iron(Ⅱ)-and Cobalt(Ⅱ)-porphyrazine with Sulfur Bridges to CdS-PVA Film

PENG Zheng-he, CHEN Xiao-gui, WANG Zheng-ping, WEI Yi-hai, QIN zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan, Hubei 430072
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project supported by the National Natural Science Foundation of China and by the State Key Laboratory of Coordination Chemistry in Nanjing University

Photosensitization of Two-dimensional Conjugated Polymers of Iron(Ⅱ)-and Cobalt(Ⅱ)-porphyrazine with Sulfur Bridges to CdS-PVA Film

PENG Zheng-he, CHEN Xiao-gui, WANG Zheng-ping, WEI Yi-hai, QIN zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan, Hubei 430072
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project supported by the National Natural Science Foundation of China and by the State Key Laboratory of Coordination Chemistry in Nanjing University

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摘要： Metal-porphyrazines (MPzs) and their polymers exhibit high thermal stability and unique photoelectric functions due to the macrocyclic planar structure and a delocalized π-electron system of the porphyrazine[1-3]. We have been found that the metal-thioporphyrazines (MSxPzs) and their conjugated polymers (PMSxPzs) have usually peculiar a gas-sensitivity, photosensitivity and electrocatalytic activity[5-8]. In the present abstract we report briefly photosensitization of the title polymers PMS8Pz (see Scheme 1) to the CdS-PVA film.

Abstract: Metal-porphyrazines (MPzs) and their polymers exhibit high thermal stability and unique photoelectric functions due to the macrocyclic planar structure and a delocalized π-electron system of the porphyrazine[1-3]. We have been found that the metal-thioporphyrazines (MSxPzs) and their conjugated polymers (PMSxPzs) have usually peculiar a gas-sensitivity, photosensitivity and electrocatalytic activity[5-8]. In the present abstract we report briefly photosensitization of the title polymers PMS8Pz (see Scheme 1) to the CdS-PVA film.

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