高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 418.

• Physical Organic Chemistry • 上一篇    下一篇

Effect and Solvent Effect on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex

CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project 29472055 supported by National Natural Science Foundation of China

Effect and Solvent Effect on Monooxygenation of Cyclohexane Catalyzed by A Dimanganese Schiff Base Complex

CHEN Xin-Bin, GUI Ming-De, ZHU Shen-Jie   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project 29472055 supported by National Natural Science Foundation of China

摘要: A new dimanganese Schiff base complex-Bis[N,N'-ethylene-2,2,-(phenylmethylene) bis (3,4-dimethyl pyrrole-5-aldimino)] dimanganese Mn2L was synthesized and used as a catalyst for PhIO oxidizing cyclohexane to cyclohexanone and cyclohexanol. This paper reports temperature effect and solvent effect on the reaction.

Abstract: A new dimanganese Schiff base complex-Bis[N,N'-ethylene-2,2,-(phenylmethylene) bis (3,4-dimethyl pyrrole-5-aldimino)] dimanganese Mn2L was synthesized and used as a catalyst for PhIO oxidizing cyclohexane to cyclohexanone and cyclohexanol. This paper reports temperature effect and solvent effect on the reaction.

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