高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 379.

• Organometallic Chemistry • 上一篇    下一篇

Theoretical Studies on Copper, Nickel Complexes of Corrole and Isocorrole

Di-Fei Wang1, Kyle W. K.. Chan1, Yun-Dong Wu1, Emanuel Vogel2   

  1. 1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong;
    2. Institut für Organische Chemie der Universität zu Köln, Greinstrasse 4, D-50939, Köln, Germany
  • 出版日期:1998-12-31 发布日期:1998-12-31

Theoretical Studies on Copper, Nickel Complexes of Corrole and Isocorrole

Di-Fei Wang1, Kyle W. K.. Chan1, Yun-Dong Wu1, Emanuel Vogel2   

  1. 1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong;
    2. Institut für Organische Chemie der Universität zu Köln, Greinstrasse 4, D-50939, Köln, Germany
  • Online:1998-12-31 Published:1998-12-31

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摘要： Corrole 2, an analogue of porphyrin 1, is also a fascinating molecule. It can be considered as an intermediate in the biosynthesis of corrin 3,the chromophore of Vitamin B12, Similar to porphyrin, corrole also has 18 electrons in the π-system of the ring and is aromatic. Recently, isocorrole 4, another compound in the corrole family, was synthesized by Vogel's group[1].One important feature of corrole and isocorrole is the possible formation of tri-anion, and thus the ability to stabilise high-oxidation-state metal cations.

Abstract: Corrole 2, an analogue of porphyrin 1, is also a fascinating molecule. It can be considered as an intermediate in the biosynthesis of corrin 3,the chromophore of Vitamin B12, Similar to porphyrin, corrole also has 18 electrons in the π-system of the ring and is aromatic. Recently, isocorrole 4, another compound in the corrole family, was synthesized by Vogel's group[1].One important feature of corrole and isocorrole is the possible formation of tri-anion, and thus the ability to stabilise high-oxidation-state metal cations.

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