高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 377.

• Organometallic Chemistry • 上一篇    下一篇

Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 5-Nitro-Phenanthroline

PENG Zheng-he, PAN Qing-cai, REN Xiao-ming, FANG Chen-jie, QIN Zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 200093
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project supported by the National Natural Science Foundation of China

Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 5-Nitro-Phenanthroline

PENG Zheng-he, PAN Qing-cai, REN Xiao-ming, FANG Chen-jie, QIN Zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 200093
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project supported by the National Natural Science Foundation of China

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被引次数

11

摘要： The dithiolenes and diimines and their metal complexes are an important research field in the organic and coordination chemistry[1-3]. Transition metal complexes of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)[3], in which are interested authors[4,5]. Recently we have been studied in detail the synthesis and properties of the title complexes M(mnt)(5-NO2-phen), M=MnⅡ, FeⅡ, CoⅡ, NiⅡ, CuⅡ, ZnⅡ. The structure and properties of the M(mnt)(5-NO2-phen) were characterized by the elemental analysis, TDA-TG, MASS, IR, UV-Vis, fluorescence and EPR spectra,molar conductivity and magnetic susceptibility. In the present abstract we report only the synthesis and spectroscopic characterization of these complexes.

Abstract: The dithiolenes and diimines and their metal complexes are an important research field in the organic and coordination chemistry[1-3]. Transition metal complexes of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)[3], in which are interested authors[4,5]. Recently we have been studied in detail the synthesis and properties of the title complexes M(mnt)(5-NO2-phen), M=MnⅡ, FeⅡ, CoⅡ, NiⅡ, CuⅡ, ZnⅡ. The structure and properties of the M(mnt)(5-NO2-phen) were characterized by the elemental analysis, TDA-TG, MASS, IR, UV-Vis, fluorescence and EPR spectra,molar conductivity and magnetic susceptibility. In the present abstract we report only the synthesis and spectroscopic characterization of these complexes.

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