高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 375.

• Organometallic Chemistry • 上一篇    下一篇

Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 4,4'-Dimethano-2,2'-bipyridine

PENG Zheng-he, FANG Chen-jie, PAN Qing-cai, WEI Yi-hai, QIN Zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 200093
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project supported by the National Natural Science Foundation of China

Synthesis and Spectroscopic Characterization of Transition Metal Complexes of Maleionitriledithiolate and 4,4'-Dimethano-2,2'-bipyridine

PENG Zheng-he, FANG Chen-jie, PAN Qing-cai, WEI Yi-hai, QIN Zi-bin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 200093
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project supported by the National Natural Science Foundation of China

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被引次数

11

摘要： Transition metal complexes with a tetragonal planar structure of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)[1-3]. Our interest is in the metal complexes of the dicyno-dithiolene and some diimine such as substituted and unsubstituted phenanthrolines and bipyridines. In the present work we studied synthesis, characterization, photo-physical and photochemical properties of the title complexes M(mnt)(dmbpy),M=MnⅡ,FeⅡ,CoⅡ, NiⅡ, CuⅡ,ZnⅡ.

Abstract: Transition metal complexes with a tetragonal planar structure of a dithiolene and a diimine have excellent electronic functions due to the intramolecular charge transfer from a ligand to other ligand (LL'CT)[1-3]. Our interest is in the metal complexes of the dicyno-dithiolene and some diimine such as substituted and unsubstituted phenanthrolines and bipyridines. In the present work we studied synthesis, characterization, photo-physical and photochemical properties of the title complexes M(mnt)(dmbpy),M=MnⅡ,FeⅡ,CoⅡ, NiⅡ, CuⅡ,ZnⅡ.

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