高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 371.

• Organometallic Chemistry • 上一篇    下一篇

Study on the α-Thiocarbonylthioformamide Ⅲ——Reaction with trimethyl phosphite

Run Sun Zeng, Jian Ping Zou, Zhong E Lu, Xiang Shan Wang, Ke Qian Chen   

  1. Department of Chemistry, Suzhou University, Suzhou 215006, Jiangsu
  • 出版日期:1998-12-31 发布日期:1998-12-31

Study on the α-Thiocarbonylthioformamide Ⅲ——Reaction with trimethyl phosphite

Run Sun Zeng, Jian Ping Zou, Zhong E Lu, Xiang Shan Wang, Ke Qian Chen   

  1. Department of Chemistry, Suzhou University, Suzhou 215006, Jiangsu
  • Online:1998-12-31 Published:1998-12-31

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2

摘要： α-Thiocarbonylthioformamide is a stable and almost unexplored class of compounds1 which attracts us to study their properties and reactions. According to literature three-valenced phosphorus compound is easy to react with thiirane2 and thiocarbonate3 to form C=C double bond. So we want to explore the reaction of α-thiocarbonylthioformamide with three-valenced phosphorus compound. In initial experiment, we explored the reaction of α-thiobenzoylthioformmorpholine (1a) with trimethyl phosphite in dry diethyl ether at room temperature.

Abstract: α-Thiocarbonylthioformamide is a stable and almost unexplored class of compounds1 which attracts us to study their properties and reactions. According to literature three-valenced phosphorus compound is easy to react with thiirane2 and thiocarbonate3 to form C=C double bond. So we want to explore the reaction of α-thiocarbonylthioformamide with three-valenced phosphorus compound. In initial experiment, we explored the reaction of α-thiobenzoylthioformmorpholine (1a) with trimethyl phosphite in dry diethyl ether at room temperature.

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