高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 353.

• Organometallic Chemistry • 上一篇    下一篇

Synthesis and Characterization of Solid Supports Containing silicon

Li Jing1, Liao Xiangjun1, Liu Hua1, Xie Qinglan1, Zhao Jun2   

  1. 1. Research Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071;
    2. Tianjin Chinese Medicine College, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31

Synthesis and Characterization of Solid Supports Containing silicon

Li Jing1, Liao Xiangjun1, Liu Hua1, Xie Qinglan1, Zhao Jun2   

  1. 1. Research Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071;
    2. Tianjin Chinese Medicine College, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31

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摘要： Combinatorial chemistry has been a new field of chemistry since 1990's.[1][2] More than 90% of researchers play their emphases on the studies of the solid supports such as P-(CH2)n-N and P-(CH2)n-O(n=1,2,3), but only a couple researchers play their emphases on the studies of the P-(CH2)n-Si(n=1,2,3). Because of the characteristic of the Si-Ar bond, we devise a series of the solid supports containing Si-Ar bond.These solid supports containing silicon were synthesized in two methods. At the same time,we also synthesized the monomer of the solid supports containing silicon or tin. The structures of these compounds were characterized by IR, elemental analysis.The synthetic routes of the solid supports containing silicon are shown in scheme 1 and the synthetic routes of the monomer of the solid supports containing silicon or tin are shown in scheme 2.

Abstract: Combinatorial chemistry has been a new field of chemistry since 1990's.[1][2] More than 90% of researchers play their emphases on the studies of the solid supports such as P-(CH2)n-N and P-(CH2)n-O(n=1,2,3), but only a couple researchers play their emphases on the studies of the P-(CH2)n-Si(n=1,2,3). Because of the characteristic of the Si-Ar bond, we devise a series of the solid supports containing Si-Ar bond.These solid supports containing silicon were synthesized in two methods. At the same time,we also synthesized the monomer of the solid supports containing silicon or tin. The structures of these compounds were characterized by IR, elemental analysis.The synthetic routes of the solid supports containing silicon are shown in scheme 1 and the synthetic routes of the monomer of the solid supports containing silicon or tin are shown in scheme 2.

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