高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 343.
• Organometallic Chemistry • 上一篇 下一篇
Yao-feng Yuan, Ling-yun Zhang, Ai-guo Hu, Su-ming Ye, Bin Wang, Ji-tao Wang
Yao-feng Yuan, Ling-yun Zhang, Ai-guo Hu, Su-ming Ye, Bin Wang, Ji-tao Wang
摘要: For several years, we have been engaged in the synthesis and coordination chemistry of ferrocenyl-containing acyl thiourea derivatives[1-2].The existence of intramolecular hydrogen bond is another interesting problem to be investigated. A series of ferrocene derivatives containing N-formyl-N'-aryl (alkyl) thiourea side chains were synthesized by treating mono- or bis ferrocenoyl isothiocyanate with various amines. It was found that intramolecular hydrogen bond between the carbonyl oxygen and the hydrogen atom on N' is common in this kind of compound. The introduction of a ferrocene fragment into the molecule often leads to its better crystallizability.
TrendMD: