高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (S1): 340.

• Organometallic Chemistry • 上一篇    下一篇

Reaction of 1,2-bis(cyclopentadienyl)tetramethyl digermane with Ru3(CO)12

Yongqiang Zhang, Baiquan Wang, Shansheng Xu, Xiuzhong Zhou   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • 出版日期:1998-12-31 发布日期:1998-12-31
  • 基金资助:
    Project was supported by National Natural Science Foundation of China and by Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

Reaction of 1,2-bis(cyclopentadienyl)tetramethyl digermane with Ru3(CO)12

Yongqiang Zhang, Baiquan Wang, Shansheng Xu, Xiuzhong Zhou   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • Online:1998-12-31 Published:1998-12-31
  • Supported by:
    Project was supported by National Natural Science Foundation of China and by Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences

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摘要： We have recently reported a novel rearrangement reaction involving an intramolecular metathesis between M-M and Fe-Fe bonds in the dinuclear iron complexes (Me2MMMe2)[η5-C5R4)Fe(CO)]2(μ-CO)2 (M=Si, Ge; R=H, Me):[1-5].In order to extend the applied range of the rearrangement reaction we tried to synthesize the digermyl briged diruthenium analogues. The results showed a great difference between them.

Abstract: We have recently reported a novel rearrangement reaction involving an intramolecular metathesis between M-M and Fe-Fe bonds in the dinuclear iron complexes (Me2MMMe2)[η5-C5R4)Fe(CO)]2(μ-CO)2 (M=Si, Ge; R=H, Me):[1-5].In order to extend the applied range of the rearrangement reaction we tried to synthesize the digermyl briged diruthenium analogues. The results showed a great difference between them.

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